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There shouldn't be a saved_games folder in the \Program Files data folder - did you add that manually? I'm surprised that the game is even able to see something placed there, but Windows User Account Control will prevent anything from being written there, which is why you get that message when you try to save it. That folder, and its contents, should probably be deleted before trying this fix:
The usual explanation for games disappearing from the load list is a corrupted index file - there'll be a file named load_index.dat in the saved_games folder (the one in \Documents), delete that and re-start the game and it should re-generate a new list with all the saves in that folder.
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