So it seems your definition of accuracy seems to be:
A = Guys he said would be good, and panned out
B = All the guys he said would be good
Accuracy = A/B
I therefore suggest that the measure of a scout's lack of accuracy might be made of two parts--guys he said would be good, who don't turn out to be + guys he did not identify as potentially good who turned out to be good, then divide this by all the players he looked at:
C = Guys he said would be good, but did not pan out
D = Guys he looked at but did not identify would be good, but who eventually became good
E = All the guys he looked at
Error Rate = (C+D)/E
This is interesting to think about to me, because the fact that the denominator is different for these two things helps frame the problem.
At the end of the day, the only thing a team really cares about above is A (the number of good players they get from their scouting department). They also want to limit "C" guys because they represent investment that has no return. Folks don't tend to talk too much of "D" players except in the abstract.
In the old days, I think scouting staffs distiguished themselves through sweat equity, meaning a scout who drove through po-dunk cities for days and days to see 1,000 players was a better scout than one who saw only 100--merely because that increased the number of guys he said would be good, and assuming all scouts are have generically the same hit-rate, would yield more "A" players.
Today, scouting is ubiquitous. Everyone sees everyone. So the impact of sweat equity is considerably less (except in some foreign scouting areas...though that is changing, too). Given that, I suspect that the actual value of one professional scout (guys who have spent their lives doing this) over another is very, very slim.
In the above, I suggest the best measure of a scout might actually be:
Value = (A-C)/(A+B+C+D) (or some weighted factor of these)
And that the differentiation between experienced scouts is which guys fit into A and D (though the numbers of As and Ds are probably about the same).
Just my complicated .02
