This is former major league pitcher Dick LeMay. It is clearly the same card issue as the one of Tom Murray above. It is a 1967 Venezuelan card. It shows LeMay with the Industriales de Valencia. He is listed with that team on the following Wikipedia page:
https://en.wikipedia.org/wiki/Catego...lencia_players
I can't explain why Murray is wearing a jersey with a name which seems incongruous with the Valencia team, though the trim on the sleeve seems the same as LeMay's. To my knowledge, there is no evidence that Murray was in any spring camp with the Astros as either a roster player or a non-roster invitee. If anyone knows of such evidence, I'd be happy to be corrected on this.
P.S. Had a thought that Perico may have been the name of an industrial firm which was the sponsor of the team at the time. Have not been able to confirm that hunch. There is a city in Venezuela by the name of Perico, but it's hundreds of miles from Valencia, so that wouldn't make sense.
P.P.S. Found the answer on why Perico was on the jersey. Perico means parakeet in Spanish. The green color of the Valencia uniform caused the team to be called "The Parakeets." Source for this conclusion was the following webpage:
http://blog.banesco.com/el-olvidado-tricampeon/
The sentence -- Aquellos Industriales, apodados "los pericos" por el color verde de su uniforme ...--- translates into that explanation.